The predictive model GC-MW (Group-Contribution method based Modified Wilson equation) proposed for LLE (Liquid-Liquid Equilibria) estimation has been described with phase-equilibrium thermodynamic fundamentals. Further, computation procedures are discussed in details for LLE of alkane + methanol + aromatic hydrocarbon ternary mixtures and LLE predicted are presented for heptane + methanol +benzene as an example.
Liquid-liquid equilibrium
Prediction
Modified Wilson equation
Ternary mixture
Alkane
Methanol
Aromatic hydrocarbon