Memoirs of the Faculty of Engineering, Yamaguchi University
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Memoirs of the Faculty of Engineering, Yamaguchi University Volume 61 Issue 1
published_at 2010-12
Correlation of vapor-liquid equilibria for mixtures containing polar molecules by regular solution model with local volume fraction
局所体積分率を用いた正則溶液モデルによる極性分子を含む混合物の気液平衡の相関
About This Article
Descriptions
The regular solution model (the Hildebrand-Scatchard equation) coupled with the Flory-Huggins equation has been extended by using the local volume fraction of Wilson to be applicable to correlate vapor-liquid equilibria (VLE) of polar mixtures. The extended regular solution model with the local volume fraction (RSM-L) has been applied to ethanol + hydrocarbon binary mixtures in a previous study and it is found that the model can be correlate VLE of the mixtures. In this study, as a continuation, RSM-L is adopted to correlate VLE of other polar binary mixtures containing ethers, ketones and water and its applicability is examined and discussed.
Creator Keywords
Regular Solution
Local Volume Fraction
Activity Coefficient
Vapor-Liquid Equilibrium
Ethanol
Hydrocarbon
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