Technology reports of the Yamaguchi University

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Technology reports of the Yamaguchi University Volume 4 Issue 5
published_at 1991-12

Synthesis and properties of 3-aminoacrylonitriles

Synthesis and properties of 3-aminoacrylonitriles
Kajigaeshi Shoji
Morino Kohji
Fujii Katsuya
Fujisaki Shizuo
Nishida Akiko
Kobayashi Takashi
fulltext
392 KB
KJ00004351139.pdf
Descriptions
3-Aminoacrylonitriles, enamines, were obtained from the reaction of 3-methoxyacrylonitrile with aliphatic amines in appropriate solvent, in sealed tube in the presence of aqueous sodium hydroxide, or under reflux, in satisfactory yields. The reactions of 3-aminoacrylonitriles with isocyanates or isothiocyanates gave 3-amino-2-cyxanoacrylamides or 3-amino-2-cyanoacrylthioamides, respectively.