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Relationship between molecular structures and normal boiling points

Memoirs of the Faculty of Engineering, Yamaguchi University Volume 63 Issue 1 Page 1-6
published_at 2012-12
A010063000101.pdf
[fulltext] 606 KB
Title
分子構造と標準沸点の関係
Relationship between molecular structures and normal boiling points
Creators Yonezawa Setsuko
Creators Kobuchi Shigetoshi
Creators Fukuchi Kenji
Creators Arai Yasuhiko
Source Identifiers
Creator Keywords
molecular structure isomer normal boiling point branching ratio binary interaction parameter Wilson parameter vapor-liquid equilibrium
An effective parameter, which can represent molecular structures, is desired to distinguish isomers. In a series of our studies, the normal boiling points are found to be useful to distinguish isomers. In this study, a branching ratio is introduced to represent molecular structures and the relationship between the branching ratios and the normal boiling points for hydrocarbons and alcohols is discussed. It is noted that the experimental normal boiling points seem to be more successful to represent the molecular structure differences and therefore to distinguish isomers.
Languages jpn
Resource Type departmental bulletin paper
Publishers 山口大学工学部
Date Issued 2012-12
File Version Version of Record
Access Rights open access
Relations
[ISSN]1345-5583
[isVersionOf] [URI]http://memoirs.lib-e.yamaguchi-u.ac.jp/
Schools 大学院理工学研究科(工学)