Contents Menu

Synthesis of 13bH-Tribenzo [a, cd, h] azulene Derivatives and 13bH-Tribenzo [a, cd, h] azaazulene Derivatives

Memoirs of the Faculty of Engineering, Yamaguchi University Volume 40 Issue 2 Page 373-381
published_at 1990-03
KJ00000156800.pdf
[fulltext] 531 KB
Title
13bH-トリベンゾ [a, cd, h] アズレン誘導体および 13bH-トリベンゾ [a, cd, h] アザアズレン誘導体の合成
Synthesis of 13bH-Tribenzo [a, cd, h] azulene Derivatives and 13bH-Tribenzo [a, cd, h] azaazulene Derivatives
Creators Kajigaeshi Shoji
Creators Maruyama Shoji
Creators Nishida Akiko
Creators Fujisaki Shizuo
Creators Noguchi Michihiko
Source Identifiers
The compound 13bH-tribenzo [a, cd, h] azulene [1] was prepared from 1-fluorenonecarboxylic acid [5] as the starting material via several steps. 8-Methyl-13bH-tribenzo [a, cd, h] azulene [3] was synthesized from other route, and the azulenylium perchlorate [4] was derived from [3] as black crystals. Furthermore, 9-ethoxy-13bH-tribenzo [a, cd, h]-5-azaazulene [22] and 8-ethoxy-13bH-tribenzo [a, cd, h]-6-azaazulene [31], novel azaazulenes incorporating fluorene moiety, were obtained from 1-ethoxycarbony 1-9-phenyl-9-fluorenol [7] and azaazulenes 9- (2-bromomethylphenyl)-9-fluorenol [3] as starting materials, respectively.
Subjects
化学 ( Other)
Languages jpn
Resource Type departmental bulletin paper
Publishers 山口大学工学部
Date Issued 1990-03
File Version Version of Record
Access Rights open access
Relations
[ISSN]0372-7661
[NCID]AN00244228
Schools 工学部