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Spectrophotometric Determination of Copper with Violuric Acid

Memoirs of the Faculty of Engineering, Yamaguchi University Volume 20 Issue 2 Page 219-222
published_at 1969
KJ00000155723.pdf
[fulltext] 213 KB
Title
ビオルル酸による銅の吸光光度定量
Spectrophotometric Determination of Copper with Violuric Acid
Creators Matsusaki Koji
Creators Harasawa Shiro
Source Identifiers
Copper with violuric acid at pH 9 formed a watersoluble yellow complex with absorption maximum at 343mμ, by which copper was spectrophotometrically determined. The sample solution containing 20~75μg of copper transffered to a 25ml volumetric flask. The pH was adjusted to 9 with 5ml of buffer solution (0.2 M H_3BO_3 and KCL : 0.05 M Na_2B_4O_7 1 : 4), and 5ml of 4.0×10^<-3> M violuric acid solution was added. After 15 minutes the absorbance was measured at 343mμ against reagent blank. The apparent molar absorptivity at 343mμ was 16200,and the sensitivity was 0.0040 μg Cu/cm^2. The mole ratio of copper to violuric acid was 1 : 4. Cations such as iron, cobalt, nickel, chromium and anions such as citrate, oxalate, thiosulfate, EDTA, cyanide ion interfered.
Subjects
工学 ( Other)
Languages jpn
Resource Type departmental bulletin paper
Publishers 山口大学工学部
Date Issued 1969
File Version Version of Record
Access Rights open access
Relations
[ISSN]0372-7661
[NCID]AN00244228
Schools 工学部