Noguchi Michihiko
Affiliate Master
Yamaguchi University
Synthesis of 13bH-Tribenzo [a, cd, h] azulene Derivatives and 13bH-Tribenzo [a, cd, h] azaazulene Derivatives
Memoirs of the Faculty of Engineering, Yamaguchi University Volume 40 Issue 2
Page 373-381
published_at 1990-03
Title
13bH-トリベンゾ [a, cd, h] アズレン誘導体および 13bH-トリベンゾ [a, cd, h] アザアズレン誘導体の合成
Synthesis of 13bH-Tribenzo [a, cd, h] azulene Derivatives and 13bH-Tribenzo [a, cd, h] azaazulene Derivatives
Creators
Kajigaeshi Shoji
Creators
Maruyama Shoji
Creators
Nishida Akiko
Creators
Fujisaki Shizuo
Source Identifiers
The compound 13bH-tribenzo [a, cd, h] azulene [1] was prepared from 1-fluorenonecarboxylic acid [5] as the starting material via several steps. 8-Methyl-13bH-tribenzo [a, cd, h] azulene [3] was synthesized from other route, and the azulenylium perchlorate [4] was derived from [3] as black crystals. Furthermore, 9-ethoxy-13bH-tribenzo [a, cd, h]-5-azaazulene [22] and 8-ethoxy-13bH-tribenzo [a, cd, h]-6-azaazulene [31], novel azaazulenes incorporating fluorene moiety, were obtained from 1-ethoxycarbony 1-9-phenyl-9-fluorenol [7] and azaazulenes 9- (2-bromomethylphenyl)-9-fluorenol [3] as starting materials, respectively.
Languages
jpn
Resource Type
departmental bulletin paper
Publishers
山口大学工学部
Date Issued
1990-03
File Version
Version of Record
Access Rights
open access
Relations
[ISSN]0372-7661
[NCID]AN00244228
Schools
工学部