Reactions of 2-Dialkylamino-5-hydroxyl-1,3-dithian-2-ylium Perchlorates

2-ジアルキルアミノ-5-ヒドロキシル-1,3-ジチアン-2-イリウム=パークロレートの反応

Reactions of 2-Dialkylamino-5-hydroxyl-1,3-dithian-2-ylium Perchlorates

Creators Fujisaki Shizuo

Creators Nishi Toru

Creators Nishida Akiko

Creators Kajigaeshi Shoji

The reactions of six-membered ring's triheterosubstituted carbonium salt, 2-dialkylamino-5-hydroxyl-1,3-dithian-2-ylium perchlorates [4] with several reagents were carried out. In particular, the reaction of [4] with sodium N, N-dimethyldithiocarbamate in methanol gave 2,3-(trithiocarbonate) propyl N, N-dialkylthiolcarbamates [7], and with thionylchloride in the presence of DMF as catalyst gave five-membered ring's trihetero-substituted carbonium ion, 4-chloromethyl-2-dialkylamino-1,3-dithiolan-2-ylium perchlorates [9].

[ISSN]0372-7661

[NCID]AN00244228