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Studies on heterocyclic analogs of azulenes. XI. Syntheses and cycloadditions of cyclohepta[4,5]pyrrolo[1,2-a]imidazoles and cyclohept[d]imidazo[1,2-a]imidazoles

Bulletin of the Chemical Society of Japan Volume 56 Issue 12 Page 3703-3714
published_at 1983-12
Title
Studies on heterocyclic analogs of azulenes. XI. Syntheses and cycloadditions of cyclohepta[4,5]pyrrolo[1,2-a]imidazoles and cyclohept[d]imidazo[1,2-a]imidazoles
Creators Abe Noritaka
Creators Nishiwaki Tarozaemon
Creators Yamamoto Hideko
Creators Kunishige Noboru
Cyclohepta[4,5]pyrrolo[1,2-a]imidazoles (1,3a-diazacyclopent[a]azulenes) (2) and cyclohept[d]imidazo[1,2-a]imidazoles (1,3a,9-triazacyclopent[a]azulenes) (6) were synthesized from 2-aminocyclohepta[b]pyrroles and 2-aminocycloheptimidazole, respectively, in moderate to good yields. Reactions of 2 and 6 with reactive acetylenes gave 2-azacyclohepta[ef]cycl[3.2.2]azines together with bis(1,3a-diazacyclopent[a]azuleno)[1,7]diaza[12]annulenes (4) and 2,3-diazacyclohepta[ef]cycl[3.2.2]azines together with bis(1,3a,9-triazacyclopent[a]azuleno)[1,7]diaza[12]annulenes (8), respectively. Reactions of 2 and 6 with electron deficient olefins gave 4 and 8, respectively. These reactions proceeded regioselectively via 1,10-dipolar intermediates.
Languages eng
Resource Type journal article
Publishers 日本化学会
Date Issued 1983-12
File Version Not Applicable (or Unknown)
Access Rights metadata only access
Relations
[ISSN]0009-2673
[NCID]AA00580132
info:doi/10.1246/bcsj.56.3703
[isVersionOf] [URI]http://www.jstage.jst.go.jp/browse/bcsj/-char/en
Schools 大学院医学系研究科(理学)