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Electrochemical synthesis of a crystalline film of tetrabutylammonium bromide

Solid state ionics Volume 178 Issue 15-18 Page 1095-1099
published_at 2007
Title
Electrochemical synthesis of a crystalline film of tetrabutylammonium bromide
Creators Nakayama Masaharu
Creators Fukuda Masaki
Creator Keywords
tetrabutylammonium bromide thin film electrodeposition solid electrolyte crystalline
An anodic oxidation of aqueous Br^- ions on platinum substrate in the presence of tetrabutylammonium (Bu_4N^+) ions leads to the formation of Br^-_3. This accompanies the self-assembly of Bu_4N^+ cations to the electrogenerated Br^-_3 anions being accumulated near the electrode surface. The deposited Br^-_3 anions can be replaced with Br^- in solution by ion exchange, resulting in a thin film of Bu_4NBr salt with high crystallinity and low electrical conductivity.
Languages eng
Resource Type journal article
Publishers Elsevier
Date Issued 2007
File Version Not Applicable (or Unknown)
Access Rights metadata only access
Relations
[ISSN]0167-2738
[NCID]AA00443404
https://doi.org/10.1016/j.ssi.2007.06.002
[isVersionOf] [URI]http://www.sciencedirect.com/science/journal/01672738
Schools 大学院理工学研究科(工学)