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Calculation of Vapor-Liquid Equilibria for the Ethylene + Polyethylene System Using an Equation of State

Memoirs of the Faculty of Engineering, Yamaguchi University Volume 50 Issue 2 Page 193-198
published_at 2000-03
A030050000214.pdf
[fulltext] 69.8 KB
Title
状態方程式によるエチレン+ポリエチレン系の気液平衡計算
Calculation of Vapor-Liquid Equilibria for the Ethylene + Polyethylene System Using an Equation of State
Creators Kobuchi Shigetoshi
Creators Fukuchi Kenji
Creators Arai Yasuhiko
Source Identifiers
Creator Keywords
Vapor-Liquid Equilibrium Equation of State Polymer Solvent Ethylene Polyethylene
An equation of state proposed by Schotte was used to calculate vapor-liquid equilibria for ethylene + polyethlene (PE) system. The logarithmic distribution function was adopted to describe the molecular weight distribution of polyethylene and vapor-liquid calculations were at 403.15K for three number-average molecular weights M^^-_n' 2.16×10^4, 2.36×10^4 and 2.78×10^4. The calculated results show fairly good agreement with the experimental data shown in the literature. The difference among M^^-_n of feed PE gives no significant change in vapor-liquid equilibria and M^^-_n distributed in vapor phase though M^^-_n distributed in liquid phasedepends on M^^-_n of feed PE.
Subjects
工学 ( Other)
Languages jpn
Resource Type departmental bulletin paper
Publishers 山口大学工学部
Date Issued 2000-03
File Version Version of Record
Access Rights open access
Relations
[ISSN]1345-5583
[NCID]AA11422756
[isVersionOf] [URI]http://memoirs.lib-e.yamaguchi-u.ac.jp/
Schools 工学部