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Molecular Design based on the characteristics of heteroatoms

Center of Instrumental Analysis, Yamaguchi University Volume 10 Page 12-14
published_at 2002
KJ00000199274.pdf
[fulltext] 231 KB
Title
<研究報告>ヘテロ原子の特性を活かした分子集合体の設計
Molecular Design based on the characteristics of heteroatoms
Creators Murafuji Toshihiro
Creators Fujimoto Naoki
Creators Nishio Kazuyoshi
Creators Sugihara Yoshikazu
Source Identifiers
Triarylbismuthanes 1a, c fully substituted with arenes each bearing a p-accepting substituent such as ester and cyano group, which are inaccessible by a conventional Grignard method, were synthesized by using the iodine-magnesium exchange of iodoarenes with isopropylmagnesium bromide. Furthermore, a convenient route to 1d using the iodine-lithium exchange of 4-iodonitrobenzene with phenyllithium was developed. Bismuthane 1b was obtained by hydrolysis of 1a under alkaline conditions. Construction of three-dimensional organometallics based on the supramolecular interaction in the crystalline states was attempted by using 1b, c and 1d.
Languages jpn
Resource Type departmental bulletin paper
Publishers 山口大学機器分析センター
Date Issued 2002
File Version Version of Record
Access Rights open access
Relations
[NCID]AN1046804X
Schools 機器分析センター