Syntheses and Thermostabilities of N-Substituted Maleimide Copolymers. III. N-lsopropylmaleimide, N-sec-Butylmaleimide and N-tert-Butylmaleimide
Technology reports of the Yamaguchi University Volume 4 Issue 2
Page 151-159
published_at 1988-12
Title
Syntheses and Thermostabilities of N-Substituted Maleimide Copolymers. III. N-lsopropylmaleimide, N-sec-Butylmaleimide and N-tert-Butylmaleimide
Creators
Oishi Tsutomu
Creators
Mooi Masaaki
Creators
Fujimoto Minoru
Creators
Doiuchi Kazunori
Source Identifiers
The objective of this study is to improve the thermostabilities of common vinyl polymers: poly [styrene (ST)] and poly [methyl methacrylate (MMA)], by using, N-substituted maleimide (RMI) [N-substituent (R), R=isopropyl (IPMI), sec-butyl (SBMI), tert-butyl (TBMI)] as a comonomer. IPMI, SBMI and TBMI were copolymerized with ST or MMA in the presence of azobisisobutyronitrile in benzene at 60℃. The thermostabilities of copolymers were investigated by thermal gravimetric (TG) analysis and differential scanning calorimetric (DSC) measurements. Softening points, initial degradation temperatures, and glass transition temperatures of copolymers rose with increasing the contents of RMI in copolymers.
Languages
eng
Resource Type
departmental bulletin paper
Publishers
山口大学工学部
Date Issued
1988-12
File Version
Version of Record
Access Rights
open access
Relations
[ISSN]0386-3433
[NCID]AA0086073X
Schools
工学部