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Equilibria and kinetics of Al(III) complex formation with semi-xylenol orange

Technology reports of the Yamaguchi University Volume 1 Issue 3 Page 393-400
published_at 1974-12
KJ00004350935.pdf
[fulltext] 404 KB
Title
Equilibria and kinetics of Al(III) complex formation with semi-xylenol orange
Creators Murakami Sadaaki
Creators Kagawa Megumi
Creators Yoshino Takashi
Source Identifiers
The equilibria and the kinetics of the A1 (III) complex formation with Semi-Xylenol Orange (SXO) in an aqueous solution have been investigated potentiometrically and spectrophotometrically. A1 (III) forms three complex species, A1SXO^-, A1HSXO and A1(OH)SXO^<2-> with SXO. The stability constants and the rate constants of these complex formations have been determined. The complex formation may proceed following the Eigen-Tamm mechanism, and the dissociation of the water molecule from the aquo ion may be the rate-determining of the complex formation.
Subjects
工学 ( Other)
Languages eng
Resource Type departmental bulletin paper
Publishers 山口大学工学部
Date Issued 1974-12
File Version Version of Record
Access Rights open access
Relations
[ISSN]0386-3433
[NCID]AA0086073X
Schools 工学部