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Low Lattice Thermal Conductivities of Sintered Type-II Clathrates (K,Ba)24(Ga,Sn)136 with Anharmonic and Disordered Guest Potentials Arising from Large Guest-Site Splitting and Ga–Sn Alloyed Frameworks

ACS Applied Energy Materials Volume 9 Issue 16 Page 10626-10636
published_at 2026-08-24
ACSApplEnergyMater2025Oct-KBaGaSn-revRR.pdf
[fulltext] 37.3 MB
Supplemental Data : https://public.oa.kenkyu.yamaguchi-u.ac.jp/cd864ba8-262b-469f-bfb5-d403a79b912e
Title
Low Lattice Thermal Conductivities of Sintered Type-II Clathrates (K,Ba)24(Ga,Sn)136 with Anharmonic and Disordered Guest Potentials Arising from Large Guest-Site Splitting and Ga–Sn Alloyed Frameworks
Creators Kishimoto Kengo
Affiliate Master Yamaguchi University
[kakenhi]15501 grid.268397.1
Creators Akai Koji
Affiliate Master Yamaguchi University
[kakenhi]15501 grid.268397.1
Source Identifiers [EISSN] 2574-0962
Creator Keywords
thermoelectric materials clathrates type-II clathrate thermal conductivity rattling guest potential site splitting
Languages eng
Resource Type journal article
Publishers American Chemical Society
Date Issued 2026-08-24
Rights
© 2026 American Chemical Society()
File Version Accepted Manuscript
Access Rights open access
Relations
[isVersionOf] 10.1021/acsaem.6c01518
[isSupplementedBy] [URI]https://public.oa.kenkyu.yamaguchi-u.ac.jp/cd864ba8-262b-469f-bfb5-d403a79b912e
Funding Refs
Japan Society for the Promotion of Science [crossref_funder]https://doi.org/10.13039/501100001691
Award High mobility thermoelectric materials: clathrates with controlled electronic structure in caged crystal structure by guest atomic orbital selection 22K04699
Funding Refs
Japan Society for the Promotion of Science [crossref_funder]https://doi.org/10.13039/501100001691
Award 低熱伝導熱電材料:4次非調和性ポテンシャルでラトリングを強化したII型クラスレート 25K08313
Remark
This document is the Accepted Manuscript version of a Published Article that appeared in final form in ACS Applied Energy Materials, copyright © 2026 American Chemical Society. To access the final published article, see ACS Articles on Request (https://pubs.acs.org/pages/authors_sharing#aor).