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Fujii Hiroyuki

Affiliate Master Yamaguchi University

Synthesis and Reactions of 3-Ethynyl-2-(Triphenylphosphoimino)-1-azaazulenes

Heterocycles Volume 74 Page 309-320
published_at 2007
2007020141.pdf
[fulltext] 287 KB
Title
Synthesis and Reactions of 3-Ethynyl-2-(Triphenylphosphoimino)-1-azaazulenes
Creators Abe Noritaka
Creators Nagamatsu Kentaro
Creators Ariyoshi Tomoyuki
Creators Fujii Hiroyuki
Creators Murakami Yoshiko
Creators Tagashira Shoji
Creators Kakehi Akikazu
3-(Trimethylsilylethynyl)- and 3-(phenylethynyl)-2-(triphenylphosphoimino)-1-azaazulenes were synthesized by the Appel reaction of the corresponding 2-amino-3-ethynyl-1-azaazulenes. Reaction of 3-(phenylethynyl)-2-(triphenylphosphoimino)-1-azaazulene (8b) with Cu(OTf)_2 gave 3-(2-oxophenethyl)-2-(triphenylphosphoimino)-1-azaazulene (11), 3-(1,2-dioxophenethyl)-2-(triphenylphosphoimino)-1-azaazulene (12), and 2-amino-3-(1,2-dioxophenethyl)-1-azaazulene (13). The structure of 13 was decided by X-ray structure analysis, and the structure of 12 was discussed by molecular orbital calculation. Reaction of 8b with aryl isocyanate in the presence of benzoyl peroxide gave 1,10-diazabenz[a]azulene derivative.
Languages eng
Resource Type journal article
Publishers 日本複素環化学研究所
Date Issued 2007
File Version Version of Record
Access Rights open access
Relations
[ISSN]0385-5414
[NCID]AA00663739
Schools 大学院医学系研究科(理学) 総合科学実験センター 大学院理工学研究科(理学)