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Noguchi Michihiko

Affiliate Master Yamaguchi University

1, 3-dipolar addition of nitrile oxides to 3a, 4-dihydro-1-isoindolinones

Technology reports of the Yamaguchi University Volume 4 Issue 1 Page 43-49
published_at 1987-12
KJ00004351094.pdf
[fulltext] 404 KB
Title
1, 3-dipolar addition of nitrile oxides to 3a, 4-dihydro-1-isoindolinones
Creators Noguchi Michihiko
Creators Kakimoto Shinji
Creators Kajigaeshi Shoji
Source Identifiers
1,3-Dipolar addition of acetonitrile oxide to 2-phenyl-3a,4-dihydro-1-isoindolinone was carried out in a stereoselective but regiorandam manner. However, the introduction of substituent, e. g., methyl group, at the 4-position of the 1H-isoindol-1-one system turned out to improve regioselectivity of the addition. The regio- and stereoselective isoxazoline synthesis was also accomplished in the reaction with other nitrile oxides. The transformation of the isoxazoline ring was also examined.
Subjects
工学 ( Other)
Languages eng
Resource Type departmental bulletin paper
Publishers 山口大学工学部
Date Issued 1987-12
File Version Version of Record
Access Rights open access
Relations
[ISSN]0386-3433
[NCID]AA0086073X
Schools 工学部