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Abe Noritaka

Affiliate Master Yamaguchi University

Reactions of 2-amino-1-azaazulenes with diphenylcyclopropenone

Heterocycles Volume 36 Issue 9 Page 1961-1964
published_at 1993
2007020158.pdf
[fulltext] 833 KB
Title
Reactions of 2-amino-1-azaazulenes with diphenylcyclopropenone
Creators Abe Noritaka
Creators Kakehi Akikazu
Reaction of 2-amino-1-azaazulene with diphenylcyclopropenone gave 1,2-diphenyl-1,2,3,10b-tetrahydro-4, 10b-diazabenz[a]azulen-3-one, which rearranged to N-(1-azaazulen-2-yl)-a-cis-stylbenecarboxamide and N-(1-azaazulen-2-yl)-a-trans-stylbenecarboxamide by heating. Some structures of these products were determined by the X-ray structure analyses. The reaction mechanism is discussed.
Languages eng
Resource Type journal article
Publishers 日本複素環化学研究所
Date Issued 1993
File Version Version of Record
Access Rights open access
Relations
[ISSN]0385-5414
[NCID]AA00663739
Schools 大学院医学系研究科(理学)