Abe Noritaka
Affiliate Master
Yamaguchi University
Reaction of 1-azaazulenes with benzyne
Journal of chemical research. Synopses Volume 2002 Issue 1
Page 8-
published_at 2002
Title
Reaction of 1-azaazulenes with benzyne
Creator Keywords
1-azaazulenes
benzyne
cycloaddition
phenylation
The reaction of 2-chloro-1-azaazulene (1a) with the benzyne prepared from (phenyl)[o-(trimethylsilyl)phenyl]iodonium triflate with tetrabutylammonium fluoride gave 1-phenyl-1-azaazulen-2(1H)-one and 8-[2-(2-chloro-1-azaazulen-6-yl)phenyl]-1-azaazulen-2(1H)-one (5), whereas the reaction of 1a with the benzyne prepared from benzenediazonium-2-carboxylate gave 6,10b-etheno-1-azabenz[e]azulen-2(3H)-one (11) together with 12.
Languages
eng
Resource Type
journal article
Publishers
Science Reviews 2000 Ltd
Date Issued
2002
File Version
Not Applicable (or Unknown)
Access Rights
metadata only access
Relations
[ISSN]0308-2342
[NCID]AA00695032
[isPartOf]
[URI]http://www.ingentaconnect.com/content/stl/jcr