Reaction of 1-azaazulenes with benzyne
Journal of Chemical Research (Miniprint) Volume 2002
Page 162-173
published_at 2002
Title
Reaction of 1-azaazulenes with benzyne
The reaction of 2-chloro-1-azaazulene (1a) with the benzyne prepared from (phenyl)[o-(trimethylsilyl)phenylliodonium triflate with tetrabutylammonium fluoride gave 1-phenyl-1-azaazulen-2(1H)-one and 8-[2-(2-chloro-1-azaazulen-6-yl)phenyl]-1-azaazulen-2(1H)-one (5), whereas the reaction of 1a with the benzyne prepared from benzenediazonium-2-carboxylate gave 6,10b-etheno-1-azabenz[e]azulen-2(1H)-one (11) together with 2-azaindeno[1,2,3-cd]aulen-1(2H)-one(12).
Languages
eng
Resource Type
journal article
Publishers
Science Reviews 2000 Ltd
Date Issued
2002
File Version
Not Applicable (or Unknown)
Access Rights
metadata only access
Relations
[ISSN]0308-2350
[NCID]AA00695021
Schools
大学院医学系研究科（理学）