Reactions of 7h-naphth[3,2,1-cd]azulen-7-ones
Perkin. 1 : an international journal of organic and bio-organic chemistry Volume 2001 Issue 12
Page 1359-1365
published_at 2001
Title
Reactions of 7h-naphth[3,2,1-cd]azulen-7-ones
6-Chloro-7H-naphth[3,2,1-cd]azulen-7-ones 9a and 10a easily react with some nucleophiles (sodium methoxide, potassium hydrosulfide, and amines) to give the corresponding 6-substituted products. Halogenation of 7H-naphth[3,2,1-cd]azulen-7-ones with N-halosuccinimides occurs at the C-5 position. Grignard reagents add to 7H-naphth[3,2,1-cd]azulen-7-ones at the seven-membered ring and a subsequent dehydrogenation gives 2-, 3- and 4-substituted products
Languages
eng
Resource Type
journal article
Publishers
Royal Society of Chemistry
Date Issued
2001
File Version
Not Applicable (or Unknown)
Access Rights
metadata only access
Relations
[ISSN]1472-7781
[NCID]AA11413675
[isVersionOf]
[URI]http://www.rsc.org/Publishing/Journals/P1/Index.asp
Schools
大学院医学系研究科（理学）