Electrochemical synthesis of a crystalline film of tetrabutylammonium bromide
Solid state ionics Volume 178 Issue 15-18
Page 1095-1099
published_at 2007
Title
Electrochemical synthesis of a crystalline film of tetrabutylammonium bromide
Creators
Fukuda Masaki
Creator Keywords
tetrabutylammonium bromide
thin film
electrodeposition
solid electrolyte
crystalline
An anodic oxidation of aqueous Br^- ions on platinum substrate in the presence of tetrabutylammonium (Bu_4N^+) ions leads to the formation of Br^-_3. This accompanies the self-assembly of Bu_4N^+ cations to the electrogenerated Br^-_3 anions being accumulated near the electrode surface. The deposited Br^-_3 anions can be replaced with Br^- in solution by ion exchange, resulting in a thin film of Bu_4NBr salt with high crystallinity and low electrical conductivity.
Languages
eng
Resource Type
journal article
Publishers
Elsevier
Date Issued
2007
File Version
Not Applicable (or Unknown)
Access Rights
metadata only access
Relations
[ISSN]0167-2738
[NCID]AA00443404
[isVersionOf]
[URI]http://www.sciencedirect.com/science/journal/01672738
Schools
大学院理工学研究科（工学）