Reactions of 2-amino-1-azaazulenes with diphenylcyclopropenone
Heterocycles Volume 36 Issue 9
Page 1961-1964
published_at 1993
Title
Reactions of 2-amino-1-azaazulenes with diphenylcyclopropenone
Creators
Kakehi Akikazu
Reaction of 2-amino-1-azaazulene with diphenylcyclopropenone gave 1,2-diphenyl-1,2,3,10b-tetrahydro-4, 10b-diazabenz[a]azulen-3-one, which rearranged to N-(1-azaazulen-2-yl)-a-cis-stylbenecarboxamide and N-(1-azaazulen-2-yl)-a-trans-stylbenecarboxamide by heating. Some structures of these products were determined by the X-ray structure analyses. The reaction mechanism is discussed.
Languages
eng
Resource Type
journal article
Publishers
日本複素環化学研究所
Date Issued
1993
File Version
Version of Record
Access Rights
open access
Relations
[ISSN]0385-5414
[NCID]AA00663739
Schools
大学院医学系研究科（理学）