Synthesis of 2-dialkylamino-5-hydroxy-1, 3-dithian-2-ylium perchlorates and their intramolecular rearrargements by use of bases
Technology reports of the Yamaguchi University Volume 4 Issue 1
Page 71-76
published_at 1987-12
Title
Synthesis of 2-dialkylamino-5-hydroxy-1, 3-dithian-2-ylium perchlorates and their intramolecular rearrargements by use of bases
Creators
Fujisaki Shizuo
Creators
Nishi Toru
Creators
Nishida Akiko
Creators
Kajigaeshi Shoji
Source Identifiers
2-Dialkylamino-5-hydroxy-1, 3-dithian-2-ylium perchlorates (2) could be synthesized by reaction of 2-alkyl-1-chloro-2, 3-epoxypropane derivertives (4) with aqueous dialkylammonium N, N-dialkyldithiocarbamates (5), followed by treatment with NaCIO4 in methanol. Reaction of 2 with bases gave 2, 3-epithiopropyl N, N-dialkylthiolcarbamates (8). In these cases, the reaction pathway involving intramolecular rearrrangement of 2 via formation of intermediate, heterobridged bicyclo compound, was proposed.
Languages
eng
Resource Type
departmental bulletin paper
Publishers
山口大学工学部
Date Issued
1987-12
File Version
Version of Record
Access Rights
open access
Relations
[ISSN]0386-3433
[NCID]AA0086073X
Schools
工学部