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Synthesis of 2-dialkylamino-5-hydroxy-1, 3-dithian-2-ylium perchlorates and their intramolecular rearrargements by use of bases

Technology reports of the Yamaguchi University Volume 4 Issue 1 Page 71-76
published_at 1987-12
KJ00004351097.pdf
[fulltext] 332 KB
Title
Synthesis of 2-dialkylamino-5-hydroxy-1, 3-dithian-2-ylium perchlorates and their intramolecular rearrargements by use of bases
Creators Fujisaki Shizuo
Creators Nishi Toru
Creators Nishida Akiko
Creators Kajigaeshi Shoji
Source Identifiers
2-Dialkylamino-5-hydroxy-1, 3-dithian-2-ylium perchlorates (2) could be synthesized by reaction of 2-alkyl-1-chloro-2, 3-epoxypropane derivertives (4) with aqueous dialkylammonium N, N-dialkyldithiocarbamates (5), followed by treatment with NaCIO4 in methanol. Reaction of 2 with bases gave 2, 3-epithiopropyl N, N-dialkylthiolcarbamates (8). In these cases, the reaction pathway involving intramolecular rearrrangement of 2 via formation of intermediate, heterobridged bicyclo compound, was proposed.
Subjects
工学 ( Other)
Languages eng
Resource Type departmental bulletin paper
Publishers 山口大学工学部
Date Issued 1987-12
File Version Version of Record
Access Rights open access
Relations
[ISSN]0386-3433
[NCID]AA0086073X
Schools 工学部