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Thiol-ester-thiono-ester rearrangements induced by alkylating reagents, peracids, or n-halosuccinimide in the 3-acylthio-4-aryl-3-isothiazoline-5-thione system

Chemistry letters Volume 9 Issue 4 Page 401-402
published_at 1980
Title
Thiol-ester-thiono-ester rearrangements induced by alkylating reagents, peracids, or n-halosuccinimide in the 3-acylthio-4-aryl-3-isothiazoline-5-thione system
Creators Nishiwaki Tarozaemon
Creators Kawamura Etsuko
Creators Abe Noritaka
Creators Iori Mitsuo
Alkylations of 3-acylthio-4-aryl-3-isothiazoline-5-thiones with diazomethane, triethyloxonium tetrafluoroborate, or alkyl iodide afford 5-alkylthio-4-aryl-3-thioacyloxyisothiazoles, whereas the reactions of these isothiazolines with peracids or N-halosuccinimide produce bis(4-aryl-3-thioacyloxyisothiazol-5-yl) disulfides.
Languages eng
Resource Type journal article
Publishers 日本化学会
Date Issued 1980
File Version Not Applicable (or Unknown)
Access Rights metadata only access
Relations
[ISSN]0366-7022
[NCID]AA00603318
https://doi.org/10.1246/cl.1980.401
[isPartOf] [URI]http://www.csj.jp/journals/chem-lett/index.html
Schools 大学院医学系研究科(理学)