Reactions of carbene conjugated with 1-azaazulene moiety : additions of 3-(2-chloro-1-azaazulenyl)methylene with cis- and trans stibenes and p-substituted styrenes to form 3-cyclopropyl-1-azaazulenes
Chemical & pharmaceutical bulletin Volume 41 Issue 4
Page 752-754
published_at 1993
Title
Reactions of carbene conjugated with 1-azaazulene moiety : additions of 3-(2-chloro-1-azaazulenyl)methylene with cis- and trans stibenes and p-substituted styrenes to form 3-cyclopropyl-1-azaazulenes
Creators
Saito Katsuhiro
Creators
Fushihara Hiroshi
Creators
Takahashi Kensuke
Creator Keywords
azaazulene
carbene
addition
cyclopropane
rate ratio
The addition reactions of 3-(2-chloro-1-azaazulenyl)methylene with cis- and trans-stilbenes proceeded in a stereospecific manner to afford the corresponding cyclopropane derivatives. The substitution effects on the relative rate ratio of the addition reactions of the carbene with styrenes having various substituents on the p-positions were measured to investigate the electronic nature of carbene.
Languages
eng
Resource Type
journal article
Publishers
日本薬学会
Date Issued
1993
File Version
Not Applicable (or Unknown)
Access Rights
metadata only access
Relations
[ISSN]0009-2363
[NCID]AA00602100
Schools
大学院医学系研究科（理学）