Abe Noritaka

Affiliate Master Yamaguchi University

Reactions of 7h-naphth[3,2,1-cd]azulen-7-ones

Perkin. 1 : an international journal of organic and bio-organic chemistry Volume 2001 Issue 12 Page 1359-1365

published_at 2001

Title

Reactions of 7h-naphth[3,2,1-cd]azulen-7-ones

Creators Abe Noritaka

Creators Fujii Hiroyuki

Creators Takase Kahei

Creators Morita Tadayoshi

6-Chloro-7H-naphth[3,2,1-cd]azulen-7-ones 9a and 10a easily react with some nucleophiles (sodium methoxide, potassium hydrosulfide, and amines) to give the corresponding 6-substituted products. Halogenation of 7H-naphth[3,2,1-cd]azulen-7-ones with N-halosuccinimides occurs at the C-5 position. Grignard reagents add to 7H-naphth[3,2,1-cd]azulen-7-ones at the seven-membered ring and a subsequent dehydrogenation gives 2-, 3- and 4-substituted products

Languages eng

Resource Type journal article

Publishers Royal Society of Chemistry

Date Issued 2001

File Version Not Applicable (or Unknown)

Access Rights metadata only access

Relations

[ISSN]1472-7781

[NCID]AA11413675

https://doi.org/10.1039/b101332g

[isVersionOf] [URI]http://www.rsc.org/Publishing/Journals/P1/Index.asp

Schools 大学院医学系研究科（理学）