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タイトルStudies on heterocyclic chemistry. Part 24. Syntheses of the 4-arylisothiazol-3-yl O-thioesters utilising the S-thioester → O-thioester rearrangements of the 4-aryl-5-thioxo-3-isothiazolin-3-yl S-Thioesters induced by acylation reagents, peracid, or N-Bromosuccinimide
作成者Nishiwaki, Tarozaemon
Kawamura, Etsuko
Abe, Noritaka
Iori, Mitsuo
作成者ヨミニシワキ, タロウザエモン
カワムラ, エツコ
アベ, ノリタカ
イオリ, ミツオ
作成者別表記阿部, 憲孝
作成者所属山口大学大学院医学系研究科(理学)
内容記述(抄録等)A number of 4-arylisothiazol-3-yl O-thioesters have been prepared utilising the S-thioester O-thioester rearrangements of the 4-aryl-5-thioxo-3-isothiazolin-3-yl S-thioesters (1). Reactions of the isothiazolines with acylation reagents (e.g. acyl chloride or acid anhydride) in the presence of boron trifluoride afforded the 5-acylthio-4-arylisothiazol-3-yl O-thioesters (2), which were also prepared by the reactions of the thallium(I) 4-aryl-5-sulphidoisothiazol-3-yl O-thioesters (3) with acyl chloride. Reactions of the isothiazolines with m-chloroperbenzoic acid gave the 5,5-dithiobis(4-arylisothiazol-3-yl O-thioesters)(5) and the 4-arylisothiazol-3-yl O-thioesters (6). The disulphides (5) were also accessible by the reaction of the isothiazolines with N-bromosuccinimide.
本文言語eng
資料タイプtext
出版者Royal Society of Chemistry
NII資料タイプ学術雑誌論文
査読の有無査読あり
ISSN0300-922X
NCIDAA00695134
掲載誌名Journal of the Chemical Society. Perkin transactions 1 : organic and bio-organic chemistry
開始ページ1401
終了ページ1406
発行日1981
関連情報URL(IsPartOf)http://www.rsc.org/Publishing/Journals/P1/
著者版/出版社版その他
リポジトリID2008010226
地域区分山口大学
URIhttp://www.lib.yamaguchi-u.ac.jp/yunoca/handle/2008010226