フルテキストURL | フルテキストリンクなし |
タイトル | Studies on heterocyclic chemistry. Part 24. Syntheses of the 4-arylisothiazol-3-yl O-thioesters utilising the S-thioester → O-thioester rearrangements of the 4-aryl-5-thioxo-3-isothiazolin-3-yl S-Thioesters induced by acylation reagents, peracid, or N-Bromosuccinimide |
作成者 | Nishiwaki, Tarozaemon
Kawamura, Etsuko
Abe, Noritaka
Iori, Mitsuo
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作成者ヨミ | ニシワキ, タロウザエモン
カワムラ, エツコ
アベ, ノリタカ
イオリ, ミツオ
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作成者別表記 | 阿部, 憲孝
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作成者所属 | 山口大学大学院医学系研究科(理学)
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内容記述(抄録等) | A number of 4-arylisothiazol-3-yl O-thioesters have been prepared utilising the S-thioester O-thioester rearrangements of the 4-aryl-5-thioxo-3-isothiazolin-3-yl S-thioesters (1). Reactions of the isothiazolines with acylation reagents (e.g. acyl chloride or acid anhydride) in the presence of boron trifluoride afforded the 5-acylthio-4-arylisothiazol-3-yl O-thioesters (2), which were also prepared by the reactions of the thallium(I) 4-aryl-5-sulphidoisothiazol-3-yl O-thioesters (3) with acyl chloride. Reactions of the isothiazolines with m-chloroperbenzoic acid gave the 5,5-dithiobis(4-arylisothiazol-3-yl O-thioesters)(5) and the 4-arylisothiazol-3-yl O-thioesters (6). The disulphides (5) were also accessible by the reaction of the isothiazolines with N-bromosuccinimide.
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本文言語 | eng
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資料タイプ | text |
出版者 | Royal Society of Chemistry
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NII資料タイプ | 学術雑誌論文 |
査読の有無 | 査読あり |
ISSN | 0300-922X
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NCID | AA00695134
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掲載誌名 | Journal of the Chemical Society. Perkin transactions 1 : organic and bio-organic chemistry |
開始ページ | 1401 |
終了ページ | 1406 |
発行日 | 1981 |
関連情報URL(IsPartOf) | http://www.rsc.org/Publishing/Journals/P1/
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著者版/出版社版 | その他 |
リポジトリID | 2008010226 |
地域区分 | 山口大学
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URI | http://www.lib.yamaguchi-u.ac.jp/yunoca/handle/2008010226 |