Japanese | English

トップページへ戻る

詳細

   
フルテキストURLフルテキストリンクなし
タイトルImmobilization of methylviologen between well-ordered multilayers of manganese oxide during their electrochemical assembly
作成者Nakayama, Masaharu
Hoyashita, Ryo
Komatsu, Hiroyuki
Muneyama, Etsuhiro
Shoda, Kaoru
Kunishige, Atsuhiro
作成者ヨミナカヤマ, マサハル
ホヤシタ, リョウ
コマツ, ヒロユキ
ムネヤマ, エツヒロ
ショウダ, カオル
クニシゲ, アツヒロ
作成者別表記中山, 雅晴
作成者所属山口大学大学院理工学研究科(工学)
内容記述(抄録等)Methylviologen dications (MV^<2+>) were immobilized between layers of manganese oxide during their electrochemical assembly by an anodic route in a homogeneous aqueous Mn^<2+> solution. This approach yielded a well-ordered multilayer film on a platinum substrate as a result of dense packing of planar MV^<2+> molecules to stabilize the layered framework. A grazing angle in-plane X-ray diffraction study revealed that the manganese oxide sheets and the molecular planes of inserted MV^<2+> ions are oriented parallel to the electrode surface. Cyclic voltammetry of the product film indicated an electron transfer from the underlying Pt substrate to inserted methylviologen ions through the manganese oxide sheets.
本文言語eng
資料タイプtext
出版者American Chemical Society
NII資料タイプ学術雑誌論文
査読の有無査読あり
ISSN0743-7463
NCIDAA10461730
掲載誌名Langmuir : the ACS journal of surfaces and colloids
23
6
開始ページ3462
終了ページ3465
発行日2007-03
DOIinfo:doi/10.1021/la062984x
関連情報URL(IsPartOf)http://pubs.acs.org/journals/langd5/index.html
著者版/出版社版その他
リポジトリID2008010091
地域区分山口大学
URIhttp://www.lib.yamaguchi-u.ac.jp/yunoca/handle/2008010091